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preservative
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Sodium Benzoate

aka benzoic acid sodium salt · E211 · benzoate

A widely used preservative in aqueous cosmetics and food. Effective against bacteria and yeast at acidic pH. Works synergistically with potassium sorbate for COSMOS-compatible broad-spectrum preservation.

Benefits
  • Broad-spectrum antimicrobial at pH <5.5
  • COSMOS-certified preservative option
  • Food-grade safety record
  • Synergistic with potassium sorbate
  • Effective against gram-negative bacteria at low pH
Example uses
  • Brightening serums (avoid with high-concentration L-ascorbic acid without metal chelation)
  • Natural certified skin care
  • K-beauty toners
  • Aqueous serums
  • Botanical mists
Formulation notes

Most effective below pH 5.5. Above pH 6, the benzoate anion (less active form) predominates. Requires potassium sorbate pairing for full spectrum in COSMOS-compliant formulations. Incompatible with formulations using iron or heavy metal co-ingredients (benzoate chelation).

Watchouts

Reacts with ascorbic acid (vitamin C) in the presence of transition metals to form benzene — a carcinogen. This reaction is concentration and condition-dependent and rarely clinically relevant in cosmetics at typical use levels, but formulations combining sodium benzoate and vitamin C should minimise transition metal co-contamination.

Clean beauty perception

Accepted in natural and COSMOS-certified formulations. EWG rating 1. One of the most widely used natural-compatible preservatives.